Diamagnetic , Paramagnetic & Ferromagnetic substance

Diamagnetic substance: Diamagnetic substances are those substances which are repelled by a magnet. From microscopic point of view, these are the substances whose atomic orbitals are completely filled. The cause of magnetization for these substances is the orbital motion of electron in which velocity of the electron is affected by the external magnetic field. Some examples of diamagnetic substances are antimony, bismuth, copper, lead, gold, silver, zinc, quartz, mercury, alcohol, sodium chloride, water, hydrogen, air, argon etc.

Properties of diamagnetic substances:

            (1)  When placed in a non-uniform magnetic field, it tends to move from stronger to weaker regions of the magnetic field. For example, when a diamagnetic liquid in a watch glass is placed on two pole pieces lying close to each other, we observe a depression in the middle and when the pole pieces are placed sufficiently apart, then we observe depressions at the sides .
diamagnetic

(2)  A diamagnetic rod when placed in a uniform magnetic field, the rod aligns itself in a direction perpendicular to the direction of the magnetic field.

(3)  The permeability of a diamagnetic substance is less than one.

(4)  When it is placed in a magnetic field, it develops weak magnetization in a direction opposite to the direction of the magnetizing field.

(5)  As soon as the magnetizing field is removed, it loses its magnetization.

(6)  The magnetic susceptibility does not depend upon temperature. It has a small negative value.

Paramagnetic substance:

Paramagnetic substances are the substances which are feebly attracted by a magnet. The atomic orbitals of these substances are partially filled and hence there exists unpaired electrons the cause of magnetisation for these materials is spin and orbital motion of electrons. Some examples include aluminium, chromium, manganese, oxygen, platinum, alkali and alkaline earth metals.
  Properties of paramagnetic substances:

 (1)  Removing the magnetizing field, the paramagnetics lose their magnetisation.

 (2)  It develops weak magnetisation along the direction of magnetic field.

(3)  The magnetic lines of force prefer to pass through the material.

(4)  When suspended freely in a uniform magnetic field, it aligns itself in the direction of  magnetic field.

(5)  It moves from weaker to stronger parts of the magnetic field.

(6)  The magnetic permeability is slightly greater than one.

Ferromagnetic substances:

These are the substances which are strongly attracted by a magnet  and can be magnetised. Ferromagnetic substances are paramagnetic in nature lent their behaviour is much more intense. Ferromagnetism can be explained on the basis of domain theory. The cause of magnetisation for these substances is the formation of domains.

(i)   Domain is a region in which magnetic moment of all atoms is in the same direction.

(ii)  At normal temperatures these domains are distributed randomly throughout the entire material. Hence net magnetic moment of the substance is zero.

Some examples of ferromagnetic substances are iron, cobalt, nickel, gadolinium, dysprosium etc.

Properties of ferromagnetic substances

(1)  When placed in a non-uniform magnetic field, it moves from weaker to stronger parts of the magnetic field. For example, when a ferromagnetic liquid in a watch glass is placed on two closely placed pole pieces, it is observed that the liquid moves the side to the middle and when the pole pieces are moved apart, the liquid gets depressed in the middle.
ferromagnetic

(2)  The magnetic lines of force tend to pass through the material.

(3)  When suspended freely in a uniform magnetic field, it aligns itself parallel to the direction of the magnetic field.

(4)  When it is placed in a magnetic field, it develops strong induced magnetism.

(5)  With the removal of the magnetizing field, it does not lose its magnetisation.

(6)  Its permeability is extremely large compared to that of free space. Hence B >> H.

(7)  Magnetic susceptibility has a very large positive value.

(8)  When placed in a magnetic field, it is strongly magnetized in the direction of the magnetic field.

(9)  The magnetic susceptibility decreases with increase of temperature. That’s why the ferromagnetism decreases with rise of temperature. Maximum at absolute zero of temperature and drops to zero at Curie temperature.

Cathode Rays & Positive Rays

Cathode rays are streams of fast moving electrons.

Properties : (i) Cathode rays are emitted normally from the cathode surface. Their direction is independent of the position of the anode.

(ii) Cathode rays travel in straight lines. (Cast shadows of objects placed in their path).

(iii) Cathode rays exert mechanical force on the objects they strike.

(iv) Cathode rays produce heat when they strike a material surface.

(v) Cathode rays produce fluorescence when they strike a number of crystals, minerals and slats.

(vi) When cathode ray strike a solid object, specially a metal, X-rays are emitted from the object. (It is not safe to use Geissler tube at potential differences above about 5–6 kV because of this X-ray emission, generated by striking of cathode rays of metal anode).

(vii) Cathode rays are deflected by an electric field and also by a magnetic field. The direction of deflection is the same as that of a stream of negatively charged particles.

(viii) Cathode rays ionize the gas through which they are passed.

(ix) Cathode rays can penetrate thin foils of metal.

(x) Cathode rays affect photographic plates.

(xi) Cathode rays are found to have velocity upto one tenth of the velocity of light. The e/m of electrons was measured by J.J. Thomson (so credit of discovering electron is given to Thomson).

The e of electron was measured by R.A./Millikan e/m = 1.759 x 1011 c/kg e = 1.602 x 10–19 C m = 9.09 x 10–31 kg

The e/m of an electron is called the specific charge of an electron.

If one includes the relativistic variation of mass with speed then specific charge of an electron decreases with the increase in the velocity of the electron.

Positive Rays :

Positive rays are sometimes known as the canal rays. These were discovered in 1896 by Goldstein. If the cathode of a discharge tube has holes in it and the pressure of the gas is around 1 mm of mercury than faint luminous glow come out from each hole on the backside of the cathode.

This shows that something is coming out of the holes. These are called canal rays or positive rays.

Positive - RAY

Origin of positive rays :

When potential difference is applied across the electrodes, electrons (cathode rays) are emitted from the cathode. As they move towards anode, they gain energy.

These energetic electrons which collide with the atoms of the gas in the discharge tube, they ionize the atoms. The positive ions formed at various places between cathode and anode, travel towards the cathode. Since during their motion, the positive ions when reach the cathode, some pass through the holes in the cathode. These stream of positive ions are the positive rays or canal rays.

If the discharge tube is totally evacuated then no positive rays are produced. Thus positive rays are positive ions of the gas in the tube. Properties of positive rays were studied by Thomson. The q/m of the hydrogen was found to be ~108 C/kg much less then the e/m of electron ~1011 C/kg indicating that mass of positive rays is much greater than that of electrons.

Properties of Positive Rays :

(i) These are positive ions having same mass if the experimental gas does not have isotopes. However if the gas has isotopes then positive rays are group of positive ions having different masses.

(ii) They travel in straight lines and cast shadows of objects placed in their path. But the speed of the positive rays is much smaller than that of cathode rays.

(iii) They are deflected by electric and magnetic fields but the deflections are small as compared to that of cathode rays.

(iv) They show a spectrum of velocities. Different positive ions move with different velocities.

(v) q/m ratio of these rays depends on the nature of the gas in the tube (while in case of the cathode rays q/m is constant and does not depend on the gas in the tube).

(vi) They carry energy and momentum.

(vii) They cause ionization (which is much more than that produced by cathode rays).

(viii) They cause fluorescence (in ZnS or CdS screen) and affect photographic plates.

(ix) They have a little penetration power (but much less in comparison to cathode rays)

Origin of X-ray & its Properties

W. C. Rontgen conducted various experi-ments to study the discharge of electricity through gases and accidently discovered X-rays.
He used a glass tube fitted with two electrodes cathode and anode. An exhaust pump was connected through a side tube and a high electric potential of about 25 kV was applied across the electrodes. Rontgen made the following important observations:

X - RAY

(a) When air inside the tube was at atmospheric pressure there was no discharge of electricity through it.

(b) When pressure inside the tube was reduced to few cm of mercury, a feeble discharge of electricity occurred between the electrodes. At the same time air inside the tube started giving visible light.

(c) When air pressure was reduced to 10–3 mm of mercury, air lumininescence gets disappeared but the glass walls of the tubes starts glowing. Rontgen concluded that this glow was due to some invisible penetrating radiations from anode that were falling on the glass and producing fluorescence. Rontgen did not know much about the nature of these rays and therefore, he called them X-rays.

(B) Explanations : Rontgen explained the production of these X-rays due to the bombardment of high velocity electrons on anode. Due to low pressure (10–3 mm) inside the tube, the air gets ionised producing a few electrons and the positive ions.

The positive ions are highly accelerated towards the cathode, these ions knock out electrons from the cathode. The released electrons move with tremendous speed towards highly positive anode. They strike the anode surface and produce X-rays. On his experimental basis, Rontgen observed that in order to produce X-rays, the following three things are required.

(a) The source of electron

(b) Means of accelerating these electrons to high speeds.

(c) Anode or target on which these high speed electrons should strike to produce X-rays.

Origin of X-ray:

X-rays are produced by bombarding high speed electrons on some heavy elements (e.g. tungsten) known as target.

A big fraction of the kinetic energy of the majority of striking electrons is spent in undergoing collisions with the atoms of the target and consequently the temperature of target material is considerably increased. It is found that nearly 99% of the incident energy of electron is used up in heating the target.
However, some fraction of the K.E. of the bombarding electrons is used up to produce X-rays in the following two ways :

CONTINUOUS X-RAYS OR BRAKING X-RAYS :

The bombarding electrons may be slowed down by the nucleus as they pass close to it , thus releasing the loss of energy in the form of X-rays.
The high speed electrons go into the interior of the atoms of the target material and are attracted by the positive charge on their Nuclei. As an electron passes lose to the positive nucleus of an atom in the target the electron is deflected from its path as shown in fig. This result in deceleration of the electron.
The loss in energy of the electron during deceleration is emitted in the form of X-rays. X-rays produced in this way are called Braking or Bremsst Rahluung X-rays as they are produced due to the braking or slowing down of the bombarding electrons by the atoms of the target.

Properties Of X-ray:

X-rays are produced when fast moving electrons (or cathode rays) strike any heavy element and have the following properties.

(1) X-rays are electromagnetic waves of very short wave length (0.03 A° to 30 A° ). Hence they carry high energy. It is to be noted here that wave length of light rays ranges from 4000 to 7500 A° . This is the only difference between X-rays and light rays.

(2) X-rays travel in straight lines like light.

(3) X-rays travel with speed of light.

(4) Just like light rays, X-rays also show the phenomenon of reflection, referaction, interference, diffraction and polarisation.

(5) X-rays are not deflected by magnetic or electric fields. Hence they are not charged particles.

(6) X-rays produce flourescence (i.e., give out light) when they fall on certain materials like zinc sulphide, glass, rock salt etc.

(7) X-rays produce continuous spectrum just like light rays.

(8) X-rays penetrate through different substant e.g. thin metal sheets, flesh etc. depending upon their frequency or energy. They do not pass through heavy metals and bones. If such objects are placed in their path, they cast their shadow.

(9) X-rays blacken the photography plate when they fall in it.

(10) X-ray ionise the gases they pass through.

(11) X-rays produce photo electric and compton effects when they fall on matter.