# Failure of Cassical Wave Theory

♦ Learning about : FAILURE OF CLASSICAL WAVE THEORY , Intensity problem ,Frequency Problem , Time delay problem , EINSTEIN’S QUANTUM THEORY OF PHOTO ELECTRIC EFFECT ♦

Intensity problem : According to wave theory intensity of a wave I ∝ E02 and so force on an electron
Fe = eE0, i.e., acceleration and hence, K.E of electron must increase with intensity. However experiments show that Kmax is independent of intensity.

Frequency Problem : According to wave theory photo electric effect should take place for all frequencies provided the intensity of light is sufficient to supply necessary energy to the electron for its emission. However, experiments on photoelectric effect reveal that for every metal there exists a frequency ν0 (depending on the nature of metal) below which no photo electric emission takes place how intense the light be.

Time delay problem : As energy in a wave is spread over the wave front, it will be absorbed by all the electrons to accumulate sufficient energy for their emission from the metal and so according to wave theory there must be a measurable time delay between incidence of light and emission of electrons. However no such time lag has ever been detected experimentally.

Above all clearly shows that photo electric effect and its characteristics can not be accounted on the basis of wave theory of light.

EINSTEIN’S QUANTUM THEORY OF PHOTO ELECTRIC EFFECT :

• In photoelectric effect, light does not behave as waves but as particles called photons.
• Photon is a energy packet, i.e., quantum of light energy with no charge and zero rest mass which transfers energy E(= hν) and momentum P(= E/c)
• Photon electric effect is the result of ‘one to one’ inelastic collision between photon and electron in which photon is completely absorbed. So if an electron in a metal absorbs a photon of energy hν.

When photon is incident on a metal surface, it transfers complete energy to an electron. Some part of energy is used to bring electron at surface and rest of energy is used to increase the K.E. of electron.

Let , Ek =Maximum kinetic energy ,

W = work function of metal ,

hν = energy absorbed by metal

From conservation of energy hν = W + Ek

⇒ Ek = hν – W

since , W = hν0

⇒    Ek = h(ν – ν0 )

⇒   (1/2) mVmax2 = h (ν – ν0) ,

If V0 = stopping potential then ,

e V0 = = h (ν – ν0)

This is known as Einstein photoelectric equation and explains photoelectric effect.