Q: Find the amount of work done to increase the temperature of 1 mol of an ideal gas by 30°C if it is expanding under the condition V ∝ T2/3.
(a) 166.2J
(b) 136.2J
(c) 126.2J
(d) none of these
Ans: (a)
Sol: As V = K T2/3
dV = K(2/3)K2/3 -1dT
dV = (2K/3)T1/3dT …(i)
On dividing
dV/V = (2/3)dT/T
As, dW = PdV
dW = (RT/V) dV
$ \displaystyle W = \int_{T_1}^{T_2} \frac{RT}{V}dV $
$ \displaystyle W = \int_{T_1}{T_2}\frac{2}{3}\frac{dT}{T} $
$ \displaystyle W = \frac{2R}{3}(T_2 – T_1) $
$ \displaystyle W = \frac{2R}{3}(30) $
W = 20R = 20 x 8.314
W = 166.28 J